Tagasi otsingusse
Kilk et al., 2010a
Solvent swelling of dictyonema oil shale
Kilk, K., Savest, N., Hruljova, J., Tearo, E., Kamenev, S., Oja, V.
DOI | 10.3176/oil.2010.1.04 |
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Aasta | 2010 |
Kirjastus | Estonian Academy Publishers |
Ajakiri | Oil Shale |
Köide | 27 |
Number | 1 |
Leheküljed | 26-36 |
Tüüp | artikkel ajakirjas |
Eesti autor | |
Keel | inglise |
Id | 11045 |
Abstrakt
The present work investigates volumetric swelling of Estonian Dictyonema oil shale, as a representative of black shales of the Baltoscandian basin, in 22 solvents. This study shows that kerogen of Dictyonema oil shale is characterized by a low degree of swelling indicating a highly cross-linked structure. The relatively high swellability in high Guttmann’s electron donor number solvents indicates the importance of non-covalent cross-links, such as hydrogen bonding, in swelling process and raises concern regarding the use of regular solution-based approaches. Despite this, the solubility parameter, a fundamental thermodynamic property, was tentatively determined from swelling data.
Viimati muudetud: 12.4.2020